The absence of CO2 in nylon-4 prepared with KOH+ radioactive CO2 catalyst

Homogeneous Catalyst Recovery and Recycle with Co2

Catalytic synthesis can be achieved by using either homogeneous or heterogeneous organometallic complexes, or homogeneous enzymatic biocatalysts. However, each of these methods offers advantages and disadvantages that must be balanced cautiously. Homogeneously catalyzed reactions are highly efficient in terms of selectivity (i.e. regioselectivity, enantiomeric excesses) and reaction rates, due ...

Law Radioactive Coupon Co2 Decontamination Test

Nano Catalyst for CO2 Conversion to Hydrocarbons

A supported trimetallic nano catalyst and a fixed bed catalytic process have been developed for the conversion of CO2 + H2O (in the form of steam) + 1% H2 to alcohol and propyne The mixture of CO2 +H2O and H2 is passed over Ru:Mn:Ni nano catalyst dispersed on a high surface area antase titanium dioxide catalyst support at 773 K and at atmospheric pressure with the gas space velocity of 6000-700...

Crystalline CO2-based polycarbonates prepared from racemic catalyst through intramolecularly interlocked assembly

The crystalline stereocomplexed polycarbonates can be prepared by mixing enantiopure polymers with opposite configuration, which derived from the asymmetric copolymerization with CO2 using enantiopure catalyst or/and chiral epoxides. Herein, we develop a powerful strategy for producing crystalline intramolecular stereocomplexed polycarbonates from racemic catalysts, which possess similar therma...

Decontamination of Radioactive Contaminants Using Liquid and Supercritical CO2